Microporous metal-organic framework containing cages with adjustable portal dimensions for adsorptive CO2 separation

摘要

The excellent breakthrough separation performance of a new microporous MOF for CO2/N-2 and CO2/CH4 gas mixtures results from the combination of different equilibrium uptake amounts depending on the adsorption enthalpies of the adsorbates and different uptake kinetics depending on their kinetic diameters.